Sorbose
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Names | |||
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IUPAC name L-xylo-Hex-2-ulose | |||
Systematic IUPAC name (3S,4R,5S)-1,3,4,5,6-Pentahydroxyhexan-2-one | |||
Other names Sorbinose L-xylo-Hexulose | |||
Identifiers | |||
CAS Number |
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3D model (JSmol) |
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ChemSpider |
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ECHA InfoCard | 100.001.611 | ||
PubChem CID |
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UNII |
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InChI
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Properties[1] | |||
Chemical formula | C6H12O6 | ||
Molar mass | 180.156 g·mol−1 | ||
Appearance | white solid | ||
Density | 1.65 g/cm3 (15 °C) | ||
Melting point | 165 °C (329 °F; 438 K) | ||
Solubility in water | Highly Soluble | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is YN ?) Infobox references |
Chemical compound
Sorbose is a ketose belonging to the group of sugars known as monosaccharides. It has a sweetness that is equivalent to sucrose (table sugar).[1] The commercial production of vitamin C (ascorbic acid) often begins with sorbose. L-Sorbose is the configuration of the naturally occurring sugar. It can be prepared from inexpensive O-benzylglucose.
Synthesis
Under conditions employed for a Meerwein-Ponndorf-Verley reduction, the tetra-O-benzyl aldose converts to tetra-O-benzylsorbose. Hydrogenolysis removes the four benzyl groups, leaving sorbose.[2]
References
- ^ a b Merck Index, 12th Edition, 8874
- ^ Frihed, Tobias Gylling; Bols, Mikael; Pedersen, Christian Marcus (2015). "Synthesis of l-Hexoses". Chemical Reviews. 115 (9): 3615–3676. doi:10.1021/acs.chemrev.5b00104. PMID 25893557.
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Types of carbohydrates
Dioses |
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Trioses |
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Tetroses |
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Pentoses |
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Hexoses | |
Heptoses |
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Above 7 |
Disaccharides | |
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Trisaccharides | |
Tetrasaccharides | |
Other oligosaccharides |
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Polysaccharides |
- Category
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